India lost 0-3 to title contenders Argentina in their last group stage encounter at the Women's Hockey World League (HWL) Semi Final here.
India will next take on England in the quarter-finals on July 18.
World No.3 Argentina were quick to get off the blocks scoring as early as the second minute. It was Rocio Sanchez who fetched Argentina an early 1-0 lead.
India's goalkeeper Savita was kept busy right from the start and unfortunately for her this goal came off Argentina's second shot on goal.
Though she made a diving effort to save the first attempt, an unmarked Sanchez was quick to pick up the rebound and convert.
Soon after, India came close to scoring an equaliser when Vandana Kataria assisted by Namita Toppo tried to deflect the ball into the goal but it was blocked by the Argentine goalkeeper.
Savita made as many as four saves in the first 15 minutes and one of her best saves was padding away a fiercely struck shot by Julieta Jankunas.
Argentina also won their first penalty corner in the sixth minute but it was blocked away by first runner Namita Toppo.
Maria Granatto scored Argentina's second goal in the 14th minute to go into the first break with a 2-0 lead.
India played the second quarter sensibly, covering their defence and restricted Argentina from entering the striking circle.
In the 23rd minute India won a penalty corner but nothing came off the opportunity as Rani's strike was well-saved by the Argentina goalkeeper.
Soon after, in the 25th minute Argentina was awarded a penalty stroke when Sushila fouled while defending a penalty corner awarded to Argentina.
The penalty stroke was converted by Noel Barrionuevo.
Argentina began the third quarter with a comfortable 3-0 lead and continued to put India under pressure.
They won back-to-back penalty corners in the 34th minute but India goalkeeper Rajani Etimarpu, who replaced Savita after half-time, along with first runner Namito Toppo did well to defend.
India came up with deep defensive tactics to keep Argentina goalless in this quarter.
The final 15 minutes saw the Indian defenders keep the Argentine attackers in check.
They didn't allow easy chances in the striking circle and came up with a high press to frustrate the Argentines.
Meanwhile, the Indian attackers made desperate attempts to take a successful shot on goal but it was hard to come by.
A tense tackle by India's Sunita Lakra resulted in Argentina being awarded a penalty corner in the dying minutes. But Rajani was brilliant with her save.
India gave away another penalty corner to Argentina soon after, this was their ninth penalty corner but nothing came off the chance.
Though Rani manufactured a great shot on goal within the final two minutes to the hooter, the Argentina goalkeeper denied India a goal as the South Americans remained unbeaten in the tournament.